Jump to content

Holmium oxyfluoride

From Wikipedia, the free encyclopedia
Holmium oxyfluoride
Names
Other names
  • Holmium oxide fluoride
  • Holmium(III) oxyfluoride
Identifiers
3D model (JSmol)
  • InChI=1S/FH.Ho.O/h1H;;/q;+3;-2/p-1
    Key: KTAGIUUVTOXAAL-UHFFFAOYSA-M
  • [F-].[Ho+3].[O-2]
Properties
HoOF
Molar mass 199.928 g/mol
Appearance crystals
Density 7.23 g/cm3
Structure
hexagonal
R3m
Related compounds
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Holmium oxyfluoride is an inorganic compound of holmium, oxygen, and fluorine with the chemical formula HoOF.[1][2]

Synthesis

[edit]

HoOF can be synthesized by pyrolyzing Ho(OH)2F from the chemical reaction between the layered Ho2(OH)5NO3 compound and NH4F in the liquid phase.[3]

Physical properties

[edit]

The compound forms crystals of the hexagonal system, space group R3m, structure type YOF.[4]

References

[edit]
  1. ^ Simons, J. H. (2 December 2012). Fluorine Chemistry V5. Elsevier. p. 99. ISBN 978-0-323-14724-8. Retrieved 15 July 2025.
  2. ^ Society, American Chemical (April 1953). Journal of the American Chemical Society. American Chemical Society. p. 2458. Retrieved 15 July 2025.
  3. ^ Cheng, Hongmei; Lu, Bin; Liu, Yongxing; Zhao, Yan; Sakka, Yoshio; Li, Ji-Guang (15 August 2019). "Transparent magneto-optical Ho2O3 ceramics: Role of self-reactive resultant oxyfluoride additive and investigation of vacuum sintering kinetics". Ceramics International. 45 (12): 14761–14767. doi:10.1016/j.ceramint.2019.04.203. ISSN 0272-8842. Retrieved 15 July 2025.
  4. ^ Donnay, Joseph Désiré Hubert (1973). Crystal Data: Inorganic compounds. National Bureau of Standards. p. 309. Retrieved 15 July 2025.